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Friday 4 September 2015

MOLE FRACTION

In chemistry, the mole fraction or molar fraction (x_i) is defined as the amount of a constituent (expressed in moles), n_i, divided by the total amount of all constituents in a mixture, n_{tot}:
x_i = \frac{n_i}{n_{tot}}
The sum of all the mole fractions is equal to 1:
\sum_{i=1}^{N} n_i = n_{tot} ; \; \sum_{i=1}^{N} x_i = 1
The same concept expressed with a denominator of 100 is the mole percent or molar percentage or molar proportion(mol%).
The mole fraction is also called the amount fraction. It is identical to the number fraction, which is defined as the number of molecules of a constituent N_i divided by the total number of all molecules N_{tot}. The mole fraction is sometimes denoted by the lowercase Greek letter χ (chi) instead of a Roman x. For mixtures of gases, IUPAC recommends the letter y.
The National Institute of Standards and Technology of the United States prefers the term amount-of-substance fractionover mole fraction because it does not contain the name of the unit mole.
Whereas mole fraction is a ratio of moles to moles, molar concentration is a ratio of moles to volume.
The mole fraction is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction(percentage by weight, wt%) and volume fraction (percentage by volume, vol%) are others.


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